ICC-vs-IUPAC by SAAD ABDUL WAHAB

Cricket VS Chemistry

ICC VS IUPAC

By SAAD ABDUL WAHAB

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NOTE: - If Man Mohan Singh wouldn’t cry before Pakistani & Srilankan rulers to beg the World Cup in order to chill the extremist & fanatic annoying Hindu sectors then the Chemical analysis of World Cup matches would be as under the comments........

Dedicated to those APPLIED SCIENTISTS & ENGINEERS, who love their profession.

ICC-vs-IUPAC

Brief discussion based on critical analysis of Pak-11 performance in "ICC WorldCup'11"

Only Chemical Engineers can understand the "Applied Chemistry of Cricket Matches" in all aspects of 360°

ICC = Initiation of Carbon Catenation

This mega event of ICC World Cup was organized to isolate the pure elemental form of world champion,

Bangladesh, Srilanka & India coordinated as hosts by providing their specially designed high capacity reactors plants, different types of contaminations required different separation techniques after going through a series of unit operations & enrichment from drilling and mining to crushing, grinding and milling, also some kind of unit processes like intra-team substitution reactions b/w unformed deactivated players & extra/reserve players,

Kenya & Nether land were separated by froth floatation of finely ground particles, multinational Canada & Ireland were also primary impurities that were removed in 1st step by density differences even without using fluxes,

Bangladesh behaved like suspended sediments and Carabians sweep them prior to super eight round,

West Indies lost shamefully by solvent extraction method in quarter final by Pak-Hawks,

English team performed superficially and removed by magnetic separation,

Dust of Kiwis by electrostatic precipitation, for this purpose a series of precipitators was used to remove them as they were exhibiting ferromagnetic nature & they crushed the pool champions of both blocks "S"&"P" (i.e., S.A & Pak),

Australian kangaroos were looking deeply impregnated in world cup so it was too difficult to remove them without using Super CO2 method at extreme conditions but practically they proved gewgaw as they quit the reaction medium by making light wt. injectible coagulates,

(Two back to back defeats by 2 Asian team)

Zimbabweans coarse trash was eliminated during earlier stages by simple vacuum filtration,

Indian team proved them MVC & they required vacuum distillation as other components (cold blooded western amphibian teams) were heat sensitive therefore reduced pressure was needed, and Pak-11 was fully equipped with refrigerants, compressors & condensers causing a see-saw condition b/w vacuum & high pressure,

South Africans were strongly bonded with victories in Pool matches, so high speed centrifuging was employed to settle down Choker Protees,

Srilankans were also removed by filtration but after precipitation by Common Ion effect, Gooch crucible suction method was essential owing to their finest particle size although we can heat them to agglomerate the fine particles but (as they were eliminated by Common Ion effect) heating may vary the Ksp or solubility product values by super saturation,

Now it was Pakistan’s turn...

Pakistani team is one & only, their degree of entropy is extremely high, they are inconsistent in all phases w.r.t performance in fielding, batting & bowling, Perhaps they don’t want to acquire the configuration of inert Australians, owing to this behavior its quite thought provoking & brain storming to speculate the exact terminal of highest potential which causes the flow of support from higher to lower concentration, their extent of homogeneity doesn’t allow gamblers to build some opinion about specificity regarding top, middle or lower order batsmen, dominated uniformity reflects the conformation of degenerated hybridized orbitals containing all bond pairs to avoid distortion, despite each player has its own individual tendency and potentiality of introducing sudden and immediate stability due to their high deviation factor, hence they've a wide range of such players who can change all properties of whole molecular team like functional groups, their players are popular for all-round performance like ">C=O" (carbonyl group) which can concurrently give various tremendous partnerships by isomerisation, each player performs pivotally by adding his branch of performance to the parent chain of score (like alkylation’s) via reforming/conversion of low octane team to high performance fuel, in order to prevent preflamation of their team by stabilizing the flash point to overcome the sudden increase in temperature due to compression of ambitions in internal combustion team engine,

Afridis strict & constructive criticism acts like catalytic converter, as he doesn’t allow players to go to the heat sink (pavilion) after incomplete combustion (performance), that’s the reason, Afridis engine (team) performs ideally like Carnot engine, after going through a series of isobaric, isochoric, isothermal & adiabatic processes, they follow all 3 "LAWS OF CONSERVATION" of fielding, batting & bowling, because if their opening partnerships couldn’t perform well then middle or lower order batting line achieves the target, similarly if batsmen failed to give "Massive" targets then bowler defend the score by high "Velocity" deliveries, thus combined effect of "Mass × Velocity" keeps the "Momentum conserved", Torque of spin deliveries is more than enough to acquire the desired Rate of return (ROR) of rival batsmen to pavilion,

When they undergo match reaction, nobody can guesstimate...

·How longer will it proceed?

·Where the equilibrium will establish?

·Match coordinates seem totally undefined,

·State functions adversely deviate, causing crucial situation,

·Unknown stoichiometric coefficients create complexity in determination of limiting reactants,

Analysts can’t speculate...

·Which one will prove him catalyst?

·In which category Pak-11 should be placed? as they act universally like H-atom, their properties resemble with most of the super eight qualified reactive teams, but not completely resemble with any one,

·The exact extent of score remains unpredictable, irrespective of the nature of pitch,

·Sometime ΔE ≈ hv = mc² cause poly-chromatic spectrum, hence nobody can approximate the exact series (Lymen, Balmer, Paschen, Pfund, Bracket), also its tricky to analyze the accurate ground & excited states of players to speculate the allowance/tolerance of outcome,

·They show Compton effect & interference phenomenon, simultaneously in both air & vacuum, and more interestingly they don’t follow the limitations of energy transfer in various mediums, they can even show conduction in air, radiation in liquids & convection in solids, as they ruined Srilanka & Australia, Srilanka & Australia ruined New Zealand & New Zealand defeated them,

·Ballers deliver a variety of swing balls like continuous flow of high speed electrons to produce intense archs on middle stumps, specially when ball suddenly turns after hitting the ground like a parallel beam of light, bends towards or away the normal (wicket) depending upon the nature of mediums, similarly their delivered balls deviate depending upon the asymmetrical hemispherical surfaces of ball (i.e. 1 side is polished and other 1 is rough) as well as uneven bounces of pitch & the spin quantum no. of ball w.r.t both, magnitude (rpm) & direction (clockwise/counter) of rotation.

·Though everybody knows... A 4 Akmal, B 4 Ball, C 4 Catch, D 4 Drop, E 4 Excuses, F 4 Fitness problems, G 4 Gambling issues, etc, etc, despite sometime he catches the ball (diffracted or bent from the sharp edge of bat) in the cavity of his gloves like a photon traps in black body, but unfortunately most of the time high temperature of his gloves cause loss/drop of photon behind the wicket,

Pak-11 suddenly changes the overall situation & conditions that could favor & shift the equilibrium on desired side. Even there’s no single sign or moment which could be rate determining, They either focus on increasing mean energy or choose some alternate path with low Ea requirement,

Sometime they behave like gases & control the desired rate constant by maximizing the fraction of effective collisions per unit volume of stadium reactor & exhibit Brownian motion of Balls across the boundaries, mostly when the match isn’t equimolar (Equi-Player) owing to the unethical & selective (I meant to say biased) intervention of umpires,

Sometime they act like liquids & snatch the victory by sudden variation in Avg.KE while the release of thermal energy may facilitate the establishment of equilibrium in their direction by means of introducing thermodynamic feasibility, also it may pyrolise even annealed lehrs of South Africans, Pyrex Srilankans & refractory producing Australians. In deformable phase they disturb all fluid mechanics by continuous deformation as well as variations in specific gravity due to their high coefficient of thermal expansion like mercury and high Q=mcΔT, its too difficult to evaluate something like ''Steady State Approximation'' on the basis of volumetric flow rate, even if accumulation=0, whereas mass flow rate may provide stoichiometric authentications by making mass-volume relationship, after equal intervals of overall match duration or full batch run time (space time)

Their fraction as well as variance of active mass is appreciably high, sometime Umer Gul starts batting & Inzimam starts Bowling,, If they won the toss, they change Law of Mass Action & prove Equilibrium Law wrong by 100% completion of reversible reactions unexpectedly, (i.e., K ≈ ∞ 'infinite'). In some cases they use both phases simultaneously around critical PVT conditions, which fail contestants strategy of choosing CSTR & PFR suitably, despite no one can predict whether...

· The composition of shots is homogenous through out the ground or merely in radial regions?

·  Concentrated in some specific quadrant, i.e., heterogeneous? Colloidal..? Owing to emulsifying action of surfactant resins (I mean singles, doubles & no boundaries), especially when BOOM BOOM isn’t facing spinners.

Their conversion rate is amazing, even they can convert Yousuf Yohana into M.Yousuf, Power plays build more pressure in reaction medium even in both intense/extreme & in mild conditions, which tends to increase batch capacity (in spite of Cv application, not Cp, i.e., ΔW=PΔV=0) or sometime it causes reverse sublimation without lowering Avg.KE & degree of warmth, The most dangerous behavior appears when they chill extremely to absolute zero & exhibit undefined density (d=∞) to beat their notorious traditional rival, abominable Indians, they knockout Indians and don’t give any space at absolute zero (i.e., Vol=0), all molecules of rivals decompose very quickly like limiting reactants and eventually start making lame excuses, such as,

·   Humidity creates problem,

·   Reactor lining (boundary line) was uneven and it was disturbing the rpm like baffle plates,

·   Pakistani bowlers act like highly coordinating multi-dendate chealeting agents, they trap our batsmen in crabs claws/chealets & don’t let us free to play independently, their fielders surround us completely like Nickel in EDTA,

·   Contaminated mixture of right & left arm players causes catalyst deactivation,

·   Absolute zero ceased molecular activity by lowering Ea, low temp didn’t facilitate reverse direction, hence equilibrium shifted to opposite side,

·   It was impossible to drive a continuous supply of work without having heat sink/conductors in the shape of substitute runners & fielders, also its impossible to drive a continuous supply of heat from a cold reservoir to hot reservoir without using the influence of external factors like gamblers, umpires or biased ICC policies,

·  Temp was dropped by other team & umpires didn’t allow us to avail abusive pressure opportunity, while referral looks risky as it may unveil our unethical aggressive body language,

·  Contact time b/w batsmen & ballers was too short, they don’t want our batsmen to stay on wickets for 3 to 5 overs,

·  Bowling speed was high due to quality of pitch, even there was zero curvature of spin balls, the path obtained by spinners balling was deviating on pitch's 2-D plane but vertically it exhibits a continuous linear function, i.e. for each run of balls path (X-Axis) there’s a unique value of -ive rise (Y-Axis),

·  Deep depression of winds disturbing elevation of shots causing fall of wickets by catches,

·  Scorching sunlight, UV radiations & sun stroke adversely affected fielder’s efficiency by producing free radicals for photolysis instead of photosynthesis; also it caused hetrolytic cleavage to introduce electronic imbalance w.r.t polarities of potentials.

·  Afridi was spitting on ball to rub it on his thigh, where an emery/sand paper was wrapped under his trouser to roughen the polished surface of ball, causing uneven bounces even at full length and good length deliveries.

·  A.Razzaq was using Aluminium bat, that cuts the stitches of balls leather and breaks the hard inner core of hard ball,

·  Pakistani players were forwarding life threats and vice versa,

Pavilion is like a boiler from which batsmen like fresh steam introduces into the grounds reactor to increase the run rate & space velocity simultaneously, sometime they steadily propagate the length of score chain from one end and sometime from both ends but seldom coupling of growing ends b/w the wickets may cause run out/fall of wicket, similarly a free radical bowler can act like terminator for the same score chain whose growth was initiated by the same radical, Pakistan is producer of terminators but itself follows step-growth polymerization of runs, in each partnership step of 30-40 mers, they lose a wicket, hence they don’t've the tendency of producing long run chains despite their innings appear highly crystalline may be due to proper seeding/stripping in runs syrup,

                                                                                                             

Contrary to Indian & English gamblers reactions, Pak team doesn’t follow those mechanisms that are designed to proceed under the influence of Intermediates or so called Umpires. Mostly their inning doesn’t appear as an elementary step, its a complex reaction mechanism, u can say, each bowling spell may be a single step that may give some idea of rate gradient at some specific instant (i.e., t=30 Overs).

In 3rd match, PAK-11 minimized the criteria of activation energy against Multinational poly-species Canada & shorten the space-time, equivalent to 85 overs, instead of 100, However a Polytheist Canadian inhibitor tried to deteriorate (retard) the activity & selectivity of AFRIDI-11 catalyst, perhaps he forgot that Pak-11 had designed full fledge feasibility to beat catalyst poisoning elements black n blue by spontaneous back to back catalytic regeneration like swing reactors, all the activated complexes were showing dynamic behaviors like transition state of sulfur crystals b/w monoclinic & rhombic polymorphs, also their specificity didn’t allow unwanted parallel reactions..

Similarly in 6th match of 1st round, and also in 1st quarter final, Pak-11 act like strong reducing agents to decrease the formal charge or oxidation no of even those compounds whose extent of ionization is ordinarily negligible (i.e., Australia & West Indies) but during reaction Pak-11 compelled them to exhibit appreciable dissociation in polar solvent of high di-electric constant, Pak-11 decomposed both compounds completely in very short time however both compounds are famous for a reason of being weak electrolytes, sparingly soluble & stable in aqueous solution,

Pak’s batsmen establish effectively & efficiently strong dipole moment b/w the 2 ends of crease and runners wave no (high frequency of "to & fro" motion b/w the wickets) strengthen the partnership bond by means of symmetric stretching vibrations,

                           

Pak-11 accomplished 7 step, match catalysis in just 2 steps by moving across the active centers neglecting carriers support & pore radii despite their high surface tension, low surface energy & open system causing full H&MT/loses by means of radiations & both (-ive/+ive) desorptions, they behave equally indifferent with all ranges of void fractions/porosities of both mono & bidisperse systems by depositing the monolayers of runs quickly to reduce the activity of contestants catalyst, also they don’t care whether the thermodynamic parameters are conformable or totally Hippocratic like Darrel Heir & David Shepherd, likewise they don’t consider the conditional effectiveness of high surface area requirement because coupling of some stable partnerships are more than enough to drag the extent of score chain reaction unpredictably in captivating, specially when there’s no steady state and accumulation b/w the wickets is comparatively stable, leaving behind the broken bridges of fielders clouds..

Sometime Pak-11 takes extra scientific measures like,

·Neglecting DALTONS LAW, their pressure becomes an intensive property, however ∑P=(n1+n2+n3+.....+nth n)RT/V

·They behave like Ideal gases despite you can expect some Deviation (Zee) Factor from their side,

·They keep Ksp constant in the shape of [Reactant]=Constant, when contestants want to acquire super saturation,

·They eliminate enemies like by products periodically even when the reaction isn’t obeying the mechanism of step-growth or condensation multimerisation.

·They've a wide range of allotropes & use them as per circumstances.

·They unveil contestants strategies just a bit earlier than end-point unlike indicators, and suddenly change their decision like reverse osmosis by employing osmotic pressure,

·Contrary to Pauli's exclusion principle u can observe all modes of simultaneous all-round performance in Pak players, hence we can say "In Pak-11 various pairs of players can have the same set of 4 quantum nos" similarly, they reject Aufbua's principle due to their entropy even regarding order of orbital energy,

·Their players are magnetic, paramagnetic (due to unpaired spin) as well as ferromagnetic like Fe, Ni, Co. More interestingly these all behaviors are simultaneous.

·Their primary & secondary bond strengths are equally very high, thatsY neither they can be degraded nor can be melted ordinarily, due to very high values of bond energies/Hf and a combination of H--OH, C6H6 resonance, induction, weak vander waal, etc

·They can follow SN¹ & E¹ reactions even in Non Polar medium in all 1°, 2° & 3° R--X compounds without any slow/rate determining step, hence nobody can guesstimate the Law of Mass Action as they don’t've slow steps in overall mechanism,

·Shoaib delivers supersonic varieties that make a cone of waves to give sonic boom.

In this respect, it’s a unique behavior & universal phenomenon of any specie that has never ever been observed anywhere,

At initiation of match reaction, very few players were exhibiting threshold, all appliedians were worried about the end products, complex intermediaries & consequences as the match kinetics were very uncertain even at fractional life T=0.5, when rate of reaction turned intensive but audience applause was extensively encouraging & Afridi was periodically asking to reverse the decisions, made by intermediaries, No doubt his confidence proved the path he chosed exclusively for this reaction was cent/cent favorable, at last after a long rigorous agitation in reactor containing both species, we heard a loud noise..

''BooM BooM...BooM BooM''

BooM BooM

And

U know what this sound stands for..??

Variables r separated, hence let’s celebrate another VICTORY w.r.t this Mega Event...!!!

Remember that its a WorldCup'11 forming reaction, sometime sudden quenching causes quick fritting, Insulated systems are more effective to accumulate the radioactivity of victories inside the reactor to prevent from decay, as they lead the world but they don’t want to be LEAD (Plumbum), after going through complete decay of heavy nucleus.

Being Asian tigers they believe in LIVING ON THE EDGE and this behavior introduces uncertainty principal, thatsY gamblers cant speculate anything with surity as reaction almost become opposite at 11th hour when UmerGul acquires the unexpected batting form (by losing his expected DUCK form) amid critical junctures and decisive or defining phases of match destiny.. Leaving behind shocked crowd still and stagnant in the shape of silent spectators. And forms a surface of slurry containing looser rivals to be separate.